NiFe2O4/m-ZrO2와 CeO2를 이용한 고온 태양열 열화학 싸이클의 수소 생산
기관명 | NDSL |
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저널명 | 한국태양에너지학회 논문집 = Journal of the Korean Solar Energy Society |
ISSN | 1598-6411, |
ISBN |
저자(한글) | 김철숙,조지현,김동연,서태범 |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2013-01-01 |
초록 | Two-step thermochemical cycle using ferrite-oxide( $Fe_2O_4$ ) device was investigated. The $H_2O$ (g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The m- $ZrO_2$ , which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30ml. And cerium oxide( $CeO_2$ ) device was used for increasing $H_2$ production rate. $CeO_2$ device had low thermal resistance, however, more $H_2$ production rate than $Fe_2O_4$ device. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=JAKO201314358630013 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | 열화학 사이클,접시형 태양열 집열 시스템,2단계 물분해,수소생산,산화세륨,페라이트 산화물,Thermochemical cycle,Dish type solar thermal system,Two-step water splitting,Hydrogen production, lt,TEX gt,$CeO_2$ lt,/TEX gt,. lt,TEX gt,$NiFe_2O_4$ lt,/TEX gt |