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A re-examination of the reaction of dichloro-tris-(triphenylphosphino)ruthenium(II) with benzonitrile: Crystal structures of triphenylphosphine chloro ruthenium complexes
논문 개요
| 기관명 | NDSL |
|---|---|
| 저널명 | Polyhedron |
| ISSN | 0277-5387,1873-3719 |
| ISBN |
논문저자 및 소속기관 정보
| 저자(한글) | Cruz, S.S.,Amenta, D.S.,Gilje, J.W.,Yap, G.P.A. |
|---|---|
| 저자(영문) | |
| 소속기관 | |
| 소속기관(영문) | |
| 출판인 | |
| 간행물 번호 | |
| 발행연도 | 2016-01-01 |
| 초록 | The reaction of RuCl 2 (PPh 3 ) 3 with benzonitrile has been investigated in toluene. When excess benzonitrile is employed cis-RuCl 2 (PPh 3 ) 2 (NCPh) 2 is obtained and has been characterized by X-ray diffraction. This contrasts to acetonitrile which yields trans-RuCl 2 (PPh 3 ) 2 (NCMe) 2 . With excess RuCl 2 (PPh 3 ) 3 a triply chloro bridged diruthenium compound (PPh 3 ) 2 (Cl)Ru( mu;-Cl) 3 Ru(NCPh)(PPh 3 ) 2 is obtained. A dark red crystalline side product, formed during the preparation of RuCl 2 (PPh 3 ) 3 , is identified as [Ph 3 PMe][RuCl 4 (PPh 3 ) 2 ] by low temperature crystal structure determination with better precision than previously reported. In each case, the Ru atom presents octahedral coordination geometry. |
| 원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=NART75761980 |
| 첨부파일 |
추가정보
| 과학기술표준분류 | |
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| ICT 기술분류 | |
| DDC 분류 | |
| 주제어 (키워드) | Ruthenium,Triphenylphosphine,Benzonitrile,Crystal structure,IR spectra |