Ni-Zn 레독스 플로우 전지에 있어서 양극의 전기화학적 특성에 미치는 쉬트 형상의 Ni 나노분말 첨가 효과
기관명 | NDSL |
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저널명 | 전기전자재료학회논문지 = Journal of the Korean institute of electronic material engineers |
ISSN | 1226-7945, |
ISBN |
저자(한글) | 석혜원,김세기,강양구,홍연우,이영진,김범수,주병권 |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2014-01-01 |
초록 | 3 mol% Co-added $Ni(OH)_2$ fine powders, which showed ${ beta}$ -phase, as positive electrode materials have been fabricated using $NiSO_4{ cdot}6H_2O$ aqueous solution by ultrasonic spray-chemical precipitation and subsequent hydrothermal method, and sheet-like Ni nanopowder was fabricated by mechano-chemical reduction method. The addition effects of the sheet-like Ni nanopowder on the electrochemical properties of the positive electrode in Ni-Zn Redox flow battery were investigated. Impedance spectroscopy revealed that the addition of the sheet-like Ni nanopowder resulted in decrease in the electrical resistivity; 10 wt.% addition reduced the electrical properties by a fifth. Cyclic voltammetry showed the addition of the sheet-like Ni nanopowder resulted in decrease in the potential difference of oxidation and reduction; this means the increase in the reversability for electrode reduction. Charge/discharge measurement confirmed that the addition of the sheet-like Ni nanopowder resulted in the increase in the discharge efficiency. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=JAKO201427542600389 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | Ni-Zn Redox flow battery,Sheet-like Ni,Co-added lt,TEX gt,$Ni(OH)_2$ lt,/TEX gt,. Impedance spectroscopy |