CBB를 첨가한 NiO 산소전달입자의 물성 및 반응 특성
기관명 | NDSL |
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저널명 | 한국수소 및 신에너지학회 논문집 = Transactions of the Korean Hydrogen and New Energy Society |
ISSN | 1738-7264, |
ISBN |
저자(한글) | 백점인,조현근,엄태형,이중범,류호정 |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2016-01-01 |
초록 | Spray-dried NiO-based oxygen carriers developed for chemical looping combustion required high calcination temperatures above $1300^{ circ}C$ to obtain high mechanical strength applicable to circulating fluidized-bed process. In this study, the effect of CBB ( $CaO{ cdot}BaO{ cdot}B_2O_3$ ) addition, as a binder, on the physical properties and oxygen transfer reactivity of spray-dried NiO-based oxygen carriers was investigated. CBB addition resulted in several positive effects such as reduction of calcination temperature and increase in oxygen transfer capacity and porosity. However, oxygen transfer rate was considerably decreased. This was more apparent when a higher amount of CBB was added and MgO was added together. From the experimental results, it is concluded that CBB added NiO-based oxygen carriers are not suitable for chemical looping combustion and a new method to reduce calcination temperature while maintaining high oxygen transfer rate of NiO-based oxygen carriers should be found out. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=JAKO201609757436805 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | 케미컬루핑연소,산소전달입자,씨비비,산화니켈,분무건조,CLC,Oxygen carrier,CBB,Nickel oxide,Spray drying |